{"created":"2023-05-15T12:21:55.252398+00:00","id":9,"links":{},"metadata":{"_buckets":{"deposit":"a5594069-c384-4a60-b05d-ab8c39e600e9"},"_deposit":{"created_by":15,"id":"9","owners":[15],"pid":{"revision_id":0,"type":"depid","value":"9"},"status":"published"},"_oai":{"id":"oai:osaka-aoyama.repo.nii.ac.jp:00000009","sets":["56:1","56:1:6"]},"author_link":["2"],"item_10002_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2009-03-31","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"48","bibliographicPageStart":"39","bibliographicVolumeNumber":"1","bibliographic_titles":[{"bibliographic_title":"大阪青山大学紀要"},{"bibliographic_title":"Journal of Osaka Aoyama University","bibliographic_titleLang":"en"}]}]},"item_10002_description_12":{"attribute_name":"論文ID（NAID）","attribute_value_mlt":[{"subitem_description":"40017377551","subitem_description_type":"Other"}]},"item_10002_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"　In the previous papers, a detailed stereochemical classification of ketones, ketols and diketones was discussed from the viewpoint of not only symmetry of the molecule but circumstances of the carbonyl group(s) incorporated in the molecule, in which these carbonyl compounds was classified into 35 types involving 19 and 16 types for achiral and chiral molecules, respectively. A new notation system using three descriptors, H(homotopic), D(diastereotopic) and E(enantiotopic) with a symbol /, was also proposed to represent stereochemical characteristics of these carbonyl compounds.\n　 In this paper, a classification of the types of the reduction reaction of carbonyl compounds has been investigated with respect to the notation system described above. Validity and usefulness of the notation system to analyse steric courses of the reduction reactions of the carbonyl compounds in order to predict the number of products as well as their chiralities have been shown using numbers of applied examples.\n(accepted. Dec. 25, 2008)","subitem_description_type":"Abstract"}]},"item_10002_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"大阪青山大学『大阪青山大学紀要』編集委員会"}]},"item_10002_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA12494683","subitem_source_identifier_type":"NCID"}]},"item_10002_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"18833543","subitem_source_identifier_type":"ISSN"}]},"item_10002_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"廣瀬, 良樹"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2012-08-10"}],"displaytype":"detail","filename":"JOAUvol1.39-48(OCR)s.pdf","filesize":[{"value":"6.4 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"JOAUvol1.39-48(OCR)s","url":"https://osaka-aoyama.repo.nii.ac.jp/record/9/files/JOAUvol1.39-48(OCR)s.pdf"},"version_id":"9b24b4a9-c75c-4423-9e56-541c7327f1d1"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"カルボニル化合物"},{"subitem_subject":"立体化学的分類"},{"subitem_subject":"分子の対称"},{"subitem_subject":"表示法"},{"subitem_subject":"立体選択的還元"},{"subitem_subject":"carbonyl compounds","subitem_subject_language":"en"},{"subitem_subject":"stereochemical classificaion","subitem_subject_language":"en"},{"subitem_subject":"symmetlry of molecule","subitem_subject_language":"en"},{"subitem_subject":"notation system","subitem_subject_language":"en"},{"subitem_subject":"stereoselective reduction","subitem_subject_language":"en"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"化合物の形と反応のかたち(Ⅲ)アルコール/ケトンの酸化還元反応の立体化学的考察","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"化合物の形と反応のかたち(Ⅲ)アルコール/ケトンの酸化還元反応の立体化学的考察"},{"subitem_title":"Shapes of compounds and types of reactions (3) Stereochemical considerations of the oxidation and reduction of alcohols/ketones","subitem_title_language":"en"}]},"item_type_id":"10002","owner":"15","path":["1","6"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-08-10"},"publish_date":"2012-08-10","publish_status":"0","recid":"9","relation_version_is_last":true,"title":["化合物の形と反応のかたち(Ⅲ)アルコール/ケトンの酸化還元反応の立体化学的考察"],"weko_creator_id":"15","weko_shared_id":-1},"updated":"2023-12-19T06:16:45.654794+00:00"}